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Vibrational spectra of Mo-exchanged zeolite materials

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Mon, 17/11/2014 - 13:56 -- hemel

Description 

The aim of this project is to compute accurate spectroscopic properties of zeolite-based materials using advanced molecular simulation tools. We focus on metal-exchanged zeolites, in particular a Molybdenum-exchanged zeolite material exhibiting the CHA topology (Mo-SSZ-13). These zeolite materials are nanoporous structures consisting of channels and cages and their particular structure and composition allows chemical reactions to take place. The addition of a cation needs special attention and various charge and spin states need to be examined. Vibrational - and to a smaller extend optical - properties will mainly be derived from time-dependent trajectories obtained via molecular dynamics (MD). The trajectories can be Fourier-transformed to power spectra exhibiting peaks at the active vibrational motions.

Budget/project

FWO G063814N (DT-DFT) FWOOPR2014004901

Period 

Thursday, 13 November, 2014 to Thursday, 30 April, 2015

Node days 

3 700.00 days

Users

K. Hemelsoet, A. Van Yperen-De Deyne

Remaining days 

0.00 days

TIER1 reference n°

2014-031

Status 

Approved

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